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Lithium arsenate, Li3AsO4

The semihydrate, 2Li3AsO4,H2O, is obtained by the action of lithium carbonate on arsenic acid. The anhydrous salt is prepared by recrystallizing this hydrate from fused lithium chloride, its density at 15° C. being 3.07. With excess of arsenic acid the normal salt yields deliquescent prisms of the dihydrogen arsenate, 2LiH2AsO4,3H2O, from which water regenerates the trilithium salt.

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